Product ID:PLHF2-2X, CUSTOM PLASMA STANDARD SINGLE (SUPP DATA)
MSDS Date:10/21/1993
FSC:6850
NIIN:00N053793
MSDS Number: BVVTK

SPEX INDUSTRIES INC

3880 PARK AVE
EDISON, NJ 08820
US

Emergency Phone: 201-549-7144;800-424-9300(CHEMTREC)

Info Phone: 201-549-7144

Preparer: VANAJA SIVAKUMAR

Cage: 07977

SPEX CERTIPREP INC

METUCHEN, NJ 08840 US

Telephone: 732-549-7144

Cage: 07977

NITRIC ACID; (HNO*3) (SARA III) (CONTAINING INGS 2 & 3)

CAS: 7697-37-2

RTECS: QU5775000

Fraction By Weight: 2%

OSHA PEL 2 PPM

ACGIH TLV: 2 PPM;4 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1,000 PPM.

CAS: 7440-58-6

RTECS: MG4600000

Fraction By Weight: <0.1%

OSHA PEL N/K

ACGIH TLV: N/K

HYDROFLUORIC ACID

CAS: 7664-39-3

RTECS: MW7875000

Fraction By Weight: <1%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 90-97%

OSHA PEL N/K

ACGIH TLV: N/K

CAUSE VIOLENT SPLATTERING. SINCE FLUORIDES ARE

RTECS: 9999999ZZ

BECAUSE FLUORIDES CAN BE DESTRUCTIVE TO THE GLASS.

RTECS: 9999999ZZ

CAUSING SPASM, INFLAMM & EDEMA. SYMPS INCL;

RTECS: 9999999ZZ

SHORTNESS OF BREATH, HEADACHE, NAUSEA & VOMITING.

RTECS: 9999999ZZ

WEAR CHEMICAL RESISTANT CLOTHING. LAB

RTECS: 9999999ZZ

FULL LENGTH FACESHIELD .

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SYMPS & HLTH HAZ FOR DILUTE NITRIC
ACID ARE EXPECTED TO BE LESS SEV THAN EXPOS TO CONC NITRIC ACID.
CONC NITRIC ACID MAY BE FATAL IF TOO MUCH IS INHALED/ABSORBED THRU
SKIN. CONC NITRIC ACID VAP/MIST I S IRRIT OF EYES, MUC MEMBS &
SKIN. IN CONT W/EYES, IT PRDCES SEV BURNS WHICH MAY RSLT IN PERM
DMG & (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:VISUAL IMPAIRMENT. ON SKIN, LIQ/CONC
VAP PRDCES IMMED, SEV & PENETRATING BURNS. CONC SOLNS CAUSE DEEP
ULCERS & STAIN SKIN A BRIGHT YELLOW/YELLOWISH BROWN COLOR. VAP &
MIST MAY ERODE EXPOS TEE TH W/PRLNG EXPOS. INGEST OF LIQ WILL CAUSE
IMMED PAIN & BURNS OF MOUTH, ESOPHAGUS & GI TRACT. INHAL MAY BE
FATAL (ING 7)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES:FLUSH W/WATER FOR AT LEAST 15 MINUTES OCCASIONALLY
LIFTING UPPER & LOWER EYELIDS. SKIN:REMOVE CONTAMINATED CLOTHING,
THEN FLUSH W/WATER FOR AT LEAST 15 MINUTES. WASH CLOTHING
THOROUGHLY BEFORE RE USE. INHAL:MOVE TO FRESH AIR. INGEST:DONOT
INDUCE VOMITING. IMMED OBTAIN MED HELP. ONLY IF PATIENT IS
CONSCIOUS, GIVE LG QTYS OF WATER/MILK. IF IRRIT CONTINUES, GET MED
ATTN IMMED.

Extinguishing Media:APPROPRIATE TO SURROUNDING FIRE CONDITIONS.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:CONC HNO*3 REACTS EXPLOSIVELY W/COMBUST
ORGANIC/READILY OXIDIZABLE MATLS SUCH AS; ALCOHOL, WOOD,
TURPENTINE, METAL PWDRS, HYDROGEN SULFIDE, ETC. CONC (SUPDAT)

Spill Release Procedures:VENT AREA. DILUTE SPILL W/WATER & NEUT W/SODA
ASH, LIMESTONE, ETC. WIPE UP & PUT INTO SEALED CNTNR FOR PROPER
DISP. WASH SPILL SITE OFF W/WATER AFTER MATL PICK UP IS COMPLETE.
WEAR CHEM RESIST GLASSES , GLOVES & CLTHG. WEAR NIOSH/MSHA APPRVD
RESP.
Neutralizing Agent:SODA ASH, LIMESTONE, ETC.

Handling and Storage Precautions:CONCENTRATED NITRIC ACID WILL ATTACK
SOME FORMS OF PLASTICS, RUBBER & COATINGS. STORE AT ROOM
TEMPERATURE. KEEP TIGHTLY SEALED WHEN NOT IN USE.
Other Precautions:IRRITANT, OXIDIZER & CORROSIVE LIQUID. AVOID
INHALATION, INGESTION & CONTACT W/EYES & SKIN.

Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORK GOGGS & (ING 10)
Other Protective Equipment:DELUGE SHOWER WHICH MEETS ANSI DESIGN
CRITERIA . HAVE IMMED AVAILABILITY OF AN EYE WASH IN CASE OF EMER.
(ING 9)
Work Hygienic Practices:WASH CAREFULLY AFTER USE.
Supplemental Safety and Health
MFR'S TRADE NAME/PART #:ELEMENT SOLUTION. EXPLO HAZ:HNO*3 IS NOT
COMBUST, BUT IS STRONG OXIDIZER & ITS HEAT OF RXN W/REDUCING
AGENTS/COMBUSTS MAY CAUSE IGNIT. CAN REACT W/METALS TO RELS FLAMM
HYDROGEN GAS. MATLS TO AVOID:AS; ALCOHOL, WOOD,TURPENTINE, METAL
PWDRS, HYDROGEN SULFIDE, ETC. CONT W/STRONG BASES WILL (ING 5)

HCC:D4
Spec Gravity:1
Solubility in Water:SOLUBLE
Appearance and Odor:TRANSPARENT W/ACRID ODOR.

Stability Indicator/Materials to Avoid:YES
CONC HNO*3 IS POWERFUL OXIDIZING AGENT. IT REACTS EXPLOSIVELY W/COMBUST
ORGANIC/READILY OXIDIZABLE MATLS SUCH (SUPDAT)
Stability Condition to Avoid:ELEVATED TEMPERATURE MAY CAUSE CONTAINERS
TO BURST & LIBERATE TOXIC OXIDES OF NITROGEN.
Hazardous Decomposition Products:WILL RELEASE TOXIC NITROGEN OXIDE
FUMES & VAPORS.

Waste Disposal Methods:CONTACT LOCAL, STATE & FEDERAL HAZARDOUS OR
CHEMICAL WASTE DISPOSAL AGENCY FOR REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.